Catalysts for decomposing ozone tail gas

The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity.     

An assessment of how distance and diesel oxidation catalyst will impact thermal decomposition behaviors of particles

Decomposition mass loss and pyrolysis products analyses of particles sampled at various locations along the tailpipe of a Euro-IV diesel engine were performed using a thermogravimetry in conjunction with Fourier transformation infrared spectrometry-mass spectrum. Diesel particles were collected at the same location with and without diesel oxidation catalyst (DOC) mounted on the test engine separately. The three poles in thermal gravity-differential thermal gravity images suggested that the decomposition process of diesel particles could be divided into three stages which correspond to the decompositions of lower boiling substances, higher boiling substances and soot respectively. It is noticed that no matter whether DOC was mounted or not, the further the particles were sampled away from the engine block, the lower the peak temperatures and the heavier the mass losses within the first two stages, which indicated that the soluble organic fraction in the particle samples increased and therefore lowering the activation energy of thermal decomposition. Hydroxyl, ammonia, C_xH_y fragments, benzene, toluene, and phenol were found to be the primary products of particle decomposition, which didn't change with the location of particle sample point. The employment of DOC increased the activation energy for particle oxidation and resulted in a higher peak temperature and lower mass loss within the first-stage. Moreover, the CO stretching bands of aldehyde and ketone at 1771 cm^?1 was only detected without a DOC, while the NO₂ peak at 1634 cm^?1 was solely noticed with the presence of DOC. Compared to the first-stage pyrolysis products, more polycyclic aromatic hydrocarbons and less C_xH_y fragments were seen in the second-stage.     

Heterojunctioned CuO/Cu2O catalyst for highly efficient ozone removal

In recent years, near surface ozone pollution, has attracted more and more attention, which necessitates the development of high efficient and low cost catalysts. In this work, CuO/Cu₂O heterojunctioned catalyst is fabricated by heating Cu₂O at high temperature, and is adopted as ozone decomposition catalyst. The results show that after Cu₂O is heated at 180°C conversion of ozone increases from 75.2% to 89.3% at mass space velocity 1,920,000 cm³/(g·hr) in dry air with 1000 ppmV ozone, which indicates that this heterojunction catalyst is one of the most efficient catalysts reported at present. Catalysts are characterized by electron paramagnetic resonance spectroscopy and ultraviolet photoelectron spectroscopy, which confirmed that the heterojunction promotes the electron transfer in the catalytic process and creates more defects and oxygen vacancies in the CuO/Cu₂O interfaces. This procedure of manufacturing heterostructures would also be applicable to other metal oxide catalysts, and it is expected to be more widely applied to the synthesis of high-efficiency heterostructured catalysts in the future.     

超声波处理石化厂剩余活性污泥

采用超声波处理石化污水处理厂的剩余活性污泥。介绍了超声波对污泥的作用机理，初步研究了超声波处理污泥的影响因素。大功率超声波可以降解生物污泥，释放出其中的有机物。小功率超声波能够改善污泥的膨胀特性、提高污泥沉淀特性和脱水能力、降低污泥的含水率，达到减量的目的。经超声波处理并简单过滤的污泥滤液，COD达到4200mg／L左右，污泥含水率由94％降至85％左右。     

贫燃条件下汽车尾气中NOx催化净化研究进展

汽车尾气排放的NOx(主要是NO)是城市大气的主要污染源之一。本综述了近l0年来贫燃条件下NOx催化转化为N2的催化剂研究进展。这些方法包括HC-SCR、NO直接催化分解、NOx吸附-还原等。讨论了不同催化剂的性能影响因素。新的负载材料MFI、MCM-41、SAPO-34的应用增强了催化剂的性能。双功能催化剂由于两种活性位的协同作用表现出较高的活性和选择性。新的纳米结构概念催化剂NOx吸附还原中发现有广泛应用。介绍了上述催化脱除NOx的各种机理并指出了今后研究的方向。     

哈尔滨等几个城市气候变化的对比分析

应用距平分析和Morlet小波变换方法对哈尔滨、石家庄、武汉、广州等4个城市1951—2004年的年均气温和夏季降水进行了对比分析，结果发现，这4个城市：（1）近50多a来气温基本上都是呈逐渐升温趋势，升温幅度都在1℃以上，其中哈尔滨的气温年变化比其他3个城市剧烈；（2）气温年代际演变特征非常明显，存在10～25a尺度的变化，在20世纪80年代前期发生气候突变；（3）近50多a夏季降水变化趋势不太一致，在空间分布上表现为波列特征；（4）夏季降水年代际变化特征非常明显，都存在10a左右尺度变化；（5）降水变化趋势与气温变化趋势不一致。     

近42年成都地区雷暴的气候统计特征

利用成都地区5个测站1959—2000年的雷暴观测资料，通过数理统计和小波分析，研究了成都地区雷暴的气候特征。结果显示：成都地区年雷暴日数较多，年际变化较大，年雷暴日数有减小的变化趋势，每10a雷暴日数减少近4d；成都地区的雷暴有很强的季节性特点，集中出现在4—9月的5个月中，而夏季6，7，8三个月占7成以上；成都地区雷暴初日普遍在4月中旬，终日普遍在10月中旬，雷暴初／终日年际间差异很大。从小波分析结果看，成都、金堂、双流和蒲江4站近42a年来雷暴日数在1982年以前有12a左右的震荡周期，1982年以后表现为6a左右的周期；都江堰的年雷暴日数分布特征和其他4个测站有较大不同，主要表现为15a的震荡周期。     

西江年最高水位的神经网络预报模型

对西江洪水发生的特征进行分析表明，洪水发生频率高，具有明显阶段性特征，并与流域面雨量密切相关。利用前期环流场、海表温度（SST）场及环流特征量资料选择初选预报因子，然后对初选预报因子作EOF分解构造综合预报因子，结合人工神经网络方法建立了西江年最高水位预报模型，并对预报模型进行独立样本试验。结果表明，该预报模型对历史样本拟合精度高，试报效果明显好于传统的逐步回归模型，可在汛期预测业务中应用。     

基于遗传算法的生命线工程网络抗震优化设计

进行网络抗震可靠性分析的目的,不仅在于定量评价生命线工程网络系统的抗震性能,更重要的是利用这种分析工具指导网络抗震性能的优化设计。以无向边权网络系统为分析对象,分别以管网造价和系统抗震可靠度作为优化目标和约束条件,建立网络系统拓扑优化模型,利用递推分解算法作为网络系统抗震可靠性分析工具,并引入系统单元的灵敏度分析,采用遗传算法求解网络系统的拓扑优化问题,从而发展了一类工程网络抗震优化设计方法。实例分析结果表明,网络系统拓扑结构与系统可靠度之间有显著的正相关关系。     

二甲亚砜热稳定性的实验研究

采用先进的绝热加速量热仪为手段,对二甲亚砜的热稳定性进行了系统研究,其内容涉及纯二甲亚砜的热稳定性、加酸碱和硫化物等杂质后二甲亚砜的热稳定性,包括初始放热温度、温升速率、温度-压力等;通过修正试验数据,消除了热惰性因子的影响;得到了二甲亚砜的热稳定性特性。研究表明,在酸、碱存在时,二甲亚砜在室温下即可发生强烈的放热反应,导致二甲亚砜的分解温度提前。该实验研究结果,对二甲亚砜的安全生产工艺过程控制具有重要参考价值。